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Isoeugenol,mixture of cis and trans
Isoeugenol,mixture of cis and trans
ChemFaces products have been cited in many studies from excellent and top scientific journals
Product Name Isoeugenol,mixture of cis and trans
Price: $30 / 20mg
CAS No.: 97-54-1
Catalog No.: CFN70230
Molecular Formula: C10H12O2
Molecular Weight: 164.2 g/mol
Purity: >=98%
Type of Compound: Phenols
Physical Desc.: Powder
Source: The leaves of Japanese red pine (Pinus densiflora Sieb. et Zucc.)
Solvent: Chloroform, Dichloromethane, Ethyl Acetate, DMSO, Acetone, etc.
Download: COA    MSDS
Similar structural: Comparison
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10 mM * 1 mL in DMSO / Inquiry / In-stock
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Description: Reference standards.
Isoeugenol,mixture of cis and trans Description
Source: The leaves of Japanese red pine (Pinus densiflora Sieb. et Zucc.)
Solvent: Chloroform, Dichloromethane, Ethyl Acetate, DMSO, Acetone, etc.
Storage: Providing storage is as stated on the product vial and the vial is kept tightly sealed, the product can be stored for up to 24 months(2-8C).

Wherever possible, you should prepare and use solutions on the same day. However, if you need to make up stock solutions in advance, we recommend that you store the solution as aliquots in tightly sealed vials at -20C. Generally, these will be useable for up to two weeks. Before use, and prior to opening the vial we recommend that you allow your product to equilibrate to room temperature for at least 1 hour.

Need more advice on solubility, usage and handling? Please email to: service@chemfaces.com

After receiving: The packaging of the product may have turned upside down during transportation, resulting in the natural compounds adhering to the neck or cap of the vial. take the vial out of its packaging and gently shake to let the compounds fall to the bottom of the vial. for liquid products, centrifuge at 200-500 RPM to gather the liquid at the bottom of the vial. try to avoid loss or contamination during handling.
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Recently, ChemFaces products have been cited in many studies from excellent and top scientific journals

Cell. 2018 Jan 11;172(1-2):249-261.e12.
doi: 10.1016/j.cell.2017.12.019.
IF=36.216(2019)

PMID: 29328914

Cell Metab. 2020 Mar 3;31(3):534-548.e5.
doi: 10.1016/j.cmet.2020.01.002.
IF=22.415(2019)

PMID: 32004475

Mol Cell. 2017 Nov 16;68(4):673-685.e6.
doi: 10.1016/j.molcel.2017.10.022.
IF=14.548(2019)

PMID: 29149595

ACS Nano. 2018 Apr 24;12(4): 3385-3396.
doi: 10.1021/acsnano.7b08969.
IF=13.903(2019)

PMID: 29553709

Nature Plants. 2016 Dec 22;3: 16206.
doi: 10.1038/nplants.2016.205.
IF=13.297(2019)

PMID: 28005066

Sci Adv. 2018 Oct 24;4(10): eaat6994.
doi: 10.1126/sciadv.aat6994.
IF=12.804(2019)

PMID: 30417089
Calculate Dilution Ratios(Only for Reference)
1 mg 5 mg 10 mg 20 mg 25 mg
1 mM 6.0901 mL 30.4507 mL 60.9013 mL 121.8027 mL 152.2533 mL
5 mM 1.218 mL 6.0901 mL 12.1803 mL 24.3605 mL 30.4507 mL
10 mM 0.609 mL 3.0451 mL 6.0901 mL 12.1803 mL 15.2253 mL
50 mM 0.1218 mL 0.609 mL 1.218 mL 2.4361 mL 3.0451 mL
100 mM 0.0609 mL 0.3045 mL 0.609 mL 1.218 mL 1.5225 mL
* Note: If you are in the process of experiment, it's need to make the dilution ratios of the samples. The dilution data of the sheet for your reference. Normally, it's can get a better solubility within lower of Concentrations.
Protocol
Structure Identification:
Journal of japan oil chemists society, 1967, 16(6):344-347.
Quantitative Analysis of the Mixture of Eugenol, cis- and trans-Isoeugenol by Gas-Liquid Chromatography with the Thermal Conductivity Detector.[Reference: WebLink]
This paper describes quantitative analysis of a mixture of eugenol, cis- and trans- isoeugenol(Isoeugenol,mixture of cis and trans) by gas-liquid chromatography with the thermal conductivity detector using silicone D.C. 550, D.O.S., Apiezone L., P.E.G. 1500 and 4000, and D.B.P. as the liquid substrates.
METHODS AND RESULTS:
The following results were observed.Every liquid substrate was used individually or in combinations of two or three. In the latter cases, the substrates were utilized in a mixed manner and in repeated coating with each of two or three substrates, resulting in the finding upon analysis that D.C. 550 and D.O.S. (mixed) gave excellent results.Twenty four samples of substrates were examined for retention time in the gas chromatograms in comparison with those of eugenol and cis- and trans- isomers of isoeugenol. Among them, carvone, acetyleugenol, diethyl phthalate, n-propyl cinnamate and showed different retention time as compared with those of homologues of eugenol. Thus these substrates indicated as usable, as the inner standard material in the quantitative analysis of gas chromatography.Upon analysis, acetyl eugenol showed migration of the acetyl group to isoeugenol in the sample, resulting in acetylisoeugenol. Carvone and n-propyl cinnamate were found as preferable rather than diethyl phthalate because of less tailing and shorter retention time in gas chromatograms. But carvone was apt to scale out in gas chromatograms even when used in low weight-ratios for a sample measured.Quantitative analysis of the sample prepared (eugenol : cis-isoeugenol : trans- isoeugenol=29.8:33. 8:36.4) was carried out within relative experimental errors of ±1.5%, using n-propyl cinnamate as an inner standard material.
CONCLUSIONS:
No transformation was seen between cis- and trans- isoeugenol in these analyzing procedures.
Journal of Analytical & Applied Pyrolysis, 1990, 18(1):59-69.
Analysis of lignin by pyrolysis-gas chromatography. I. Effect of inorganic substances on guaiacol-derivative yield from softwoods and their lignins.[Reference: WebLink]

METHODS AND RESULTS:
To obtain lignin-derived pyrolysis products in larger yields, Curie-point pyrolysis was performed on the softwood species Japanese red pine (Pinus densiflora Sieb. et Zucc.), Japanese cedar (Cryptomeria japonica D. Don) and Japanese cypress (Chamaecyparis obtusa Endl.), and their dioxane lignins treated with various inorganic substances, over the temperature range 358-764.degree. C. The resulting guaiacol derivatives (guaiacol, 4-methyl-, 4-ethyl- and 4-vinylguaiacols, eugenol, vanillin, cis- and trans-isoeugenol(Isoeugenol,mixture of cis and trans), and acetovanillone) were determined by gas chromatography. The softwood samples sandwiched between two sheets of heat-resistant filter paper made of borosilicate glass fibers yielded from 1.56 to 1.64 times more guaiacol derivatives than unsandwiched samples. Sandwiching the dioxane lignins between heat-resistant papers also increased the guaiacol-derivative yield, by 13 to 27%.
CONCLUSIONS:
The sandwich-2 method developed in this study is widely applicable as a sample preparation method for increasing the yield of lignin-derived products on Curie-point pyrolysis.
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