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1,2:4,5-Di-O-isopropylidene-beta-D-fructopyranose
1,2:4,5-Di-O-isopropylidene-beta-D-fructopyranose
ChemFaces products have been cited in many studies from excellent and top scientific journals
Product Name 1,2:4,5-Di-O-isopropylidene-beta-D-fructopyranose
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CAS No.: 25018-67-1
Catalog No.: CFN98273
Molecular Formula: C12H20O6
Molecular Weight: 260.3 g/mol
Purity: >=98%
Type of Compound: Saccharides
Physical Desc.: Cryst.
Source: The herbs of Euphorbia macroclada.
Solvent: Chloroform, Dichloromethane, Ethyl Acetate, DMSO, Acetone, etc.
Download: COA    MSDS    SDF    Manual
Similar structural: Comparison (Web)  (SDF)
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Description: 1,2:4,5-di-O-isopropylidene-beta-D-fructopyranose is a synthetic precursor of the asymmetric epoxidation catalyst 1,2:4,5-di-O-isopropylidene-beta-D-erythro-2,3- hexadiulo-2,6-pyranose.
1,2:4,5-Di-O-isopropylidene-beta-D-fructopyranose Description
Source: The herbs of Euphorbia macroclada.
Solvent: Chloroform, Dichloromethane, Ethyl Acetate, DMSO, Acetone, etc.
Storage: Providing storage is as stated on the product vial and the vial is kept tightly sealed, the product can be stored for up to 24 months(2-8C).

Wherever possible, you should prepare and use solutions on the same day. However, if you need to make up stock solutions in advance, we recommend that you store the solution as aliquots in tightly sealed vials at -20C. Generally, these will be useable for up to two weeks. Before use, and prior to opening the vial we recommend that you allow your product to equilibrate to room temperature for at least 1 hour.

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Recently, ChemFaces products have been cited in many studies from excellent and top scientific journals
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Cell. 2018 Jan 11;172(1-2):249-261.e12.
doi: 10.1016/j.cell.2017.12.019.
IF=36.216(2019)

PMID: 29328914

Cell Metab. 2020 Mar 3;31(3):534-548.e5.
doi: 10.1016/j.cmet.2020.01.002.
IF=22.415(2019)

PMID: 32004475

Mol Cell. 2017 Nov 16;68(4):673-685.e6.
doi: 10.1016/j.molcel.2017.10.022.
IF=14.548(2019)

PMID: 29149595

ACS Nano. 2018 Apr 24;12(4): 3385-3396.
doi: 10.1021/acsnano.7b08969.
IF=13.903(2019)

PMID: 29553709

Nature Plants. 2016 Dec 22;3: 16206.
doi: 10.1038/nplants.2016.205.
IF=13.297(2019)

PMID: 28005066

Sci Adv. 2018 Oct 24;4(10): eaat6994.
doi: 10.1126/sciadv.aat6994.
IF=12.804(2019)

PMID: 30417089
Calculate Dilution Ratios(Only for Reference)
1 mg 5 mg 10 mg 20 mg 25 mg
1 mM 3.8417 mL 19.2086 mL 38.4172 mL 76.8344 mL 96.043 mL
5 mM 0.7683 mL 3.8417 mL 7.6834 mL 15.3669 mL 19.2086 mL
10 mM 0.3842 mL 1.9209 mL 3.8417 mL 7.6834 mL 9.6043 mL
50 mM 0.0768 mL 0.3842 mL 0.7683 mL 1.5367 mL 1.9209 mL
100 mM 0.0384 mL 0.1921 mL 0.3842 mL 0.7683 mL 0.9604 mL
* Note: If you are in the process of experiment, it's need to make the dilution ratios of the samples. The dilution data of the sheet for your reference. Normally, it's can get a better solubility within lower of Concentrations.
Protocol
Structure Identification:
Org Lett. 2002 May 16;4(10):1659-61.
Selective ruthenium-catalyzed oxidation of 1,2:4,5-di-O-isopropylidene- beta-D-fructopyranose and other alcohols with NaOCl.[Pubmed: 12000267]

METHODS AND RESULTS:
The asymmetric epoxidation catalyst 1,2:4,5-di-O-isopropylidene-beta-D-erythro-2,3-hexadiulo-2,6-pyranose 2 was obtained in high yield from 1,2:4,5-Di-O-isopropylidene-beta-D-fructopyranose 1 via a recyclable ruthenium-catalyzed hypochlorite oxidation protocol under biphasic conditions (MTBE/water) in the presence of an alkaline buffer (pH 9.5). Other secondary alcohols were also oxidized selectively to the corresponding ketones.
CFN99849Ethyl beta-D-fructofuranoside1820-84-4208.2 C8H16O6
CFN93003D-Arabinose10323-20-3150.1C5H10O5
CFN99911D-(+)-Xylose58-86-6150.13C5H10O5
CFN900781,5-Anhydro-D-glucitol154-58-5164.16C6H12O5
CFN98121Fructose57-48-7180.16C6H12O6
CFN971411,2-O-Isopropylidene-beta-D-fructopyranose66900-93-4220.2 C9H16O6
CFN982731,2:4,5-Di-O-isopropylidene-beta-D-fructopyranose25018-67-1260.3 C12H20O6
CFN90450alpha-L-Rhamnose3615-41-6164.16C6H12O5
CFN99545L-Rhamnose6155-35-7182.17C6H14O6
CFN90954D-(+)-Fucose3615-37-0164.16C6H12O5
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