Phlorin | CAS:28217-60-9 | Manufacturer ChemFaces

Phlorin

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Size /Price /Stock	10 mM * 1 mL in DMSO / Inquiry
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Phlorin Description

Source:	The herbs of Thymus vulgaris
Solvent:	DMSO, Pyridine, Methanol, Ethanol, etc.
Storage:	Providing storage is as stated on the product vial and the vial is kept tightly sealed, the product can be stored for up to 24 months(2-8C). Wherever possible, you should prepare and use solutions on the same day. However, if you need to make up stock solutions in advance, we recommend that you store the solution as aliquots in tightly sealed vials at -20C. Generally, these will be useable for up to two weeks. Before use, and prior to opening the vial we recommend that you allow your product to equilibrate to room temperature for at least 1 hour. Need more advice on solubility, usage and handling? Please email to: service@chemfaces.com
After receiving:	The packaging of the product may have turned upside down during transportation, resulting in the natural compounds adhering to the neck or cap of the vial. take the vial out of its packaging and gently shake to let the compounds fall to the bottom of the vial. for liquid products, centrifuge at 200-500 RPM to gather the liquid at the bottom of the vial. try to avoid loss or contamination during handling.

Structure Identification:

Inorg Chem. 2015 Apr 6;54(7):3501-12.

Electrochemical and spectroelectrochemical studies of diphosphorylated metalloporphyrins. Generation of a phlorin anion product.[Pubmed: 25789714]

METHODS AND RESULTS:
The free-base and five metalated porphyrins with nonredox active centers undergo two ring-centered oxidations and two ring-centered reductions, the latter of which is followed by a chemical reaction of the porphyrin dianion to give an anionic Phlorin product. The Phlorin anion is electroactive and can be reoxidized by two electrons to give back the starting porphyrin, or it can be reversibly reduced by one electron at more negative potentials to give a Phlorin dianion. The chemical conversion of the porphyrin dianion to a Phlorin anion proceeds at a rate that varies with the nature of the central metal ion and the solvent. This rate is slowest in the basic solvent pyridine as compared to CH2Cl2 and PhCN, giving further evidence for the involvement of protons in the chemical reaction leading to Phlorin formation. Calculations of the electronic structure were performed on the Ni(II) porphyrin dianion, and the most favorable atoms for electrophilic attack were determined to be the two phosphorylated carbon atoms.
CONCLUSIONS:
Phlorin formation was not observed after the two-electron reduction of the cobalt porphyrins due to the different oxidation state assignment of the doubly reduced species, a Co(I) π anion radical in one case and an M(II) dianion for all of the other derivatives. Each redox reaction was monitored by thin-layer UV-visible spectroelectrochemistry, and an overall mechanism for each electron transfer is proposed on the basis of these data.

Product Name	Phlorin
Price:
CAS No.:	28217-60-9
Catalog No.:	CFN98343
Molecular Formula:	C₁₂H₁₆O₈
Molecular Weight:	288.3 g/mol
Purity:	>=98%
Type of Compound:	Phenols
Physical Desc.:	Powder
Source:	The herbs of Thymus vulgaris
Solvent:	DMSO, Pyridine, Methanol, Ethanol, etc.
Download:	COA MSDS SDF Manual
Similar structural:	Comparison (Web) (SDF)
Guestbook:

Size /Price /Stock	10 mM * 100 uL in DMSO / Inquiry / In-stock 10 mM * 1 mL in DMSO / Inquiry / In-stock
Related Libraries	Phenols Compound Library

	1 mg	5 mg	10 mg	20 mg	25 mg
1 mM	3.4686 mL	17.343 mL	34.6861 mL	69.3722 mL	86.7152 mL
5 mM	0.6937 mL	3.4686 mL	6.9372 mL	13.8744 mL	17.343 mL
10 mM	0.3469 mL	1.7343 mL	3.4686 mL	6.9372 mL	8.6715 mL
50 mM	0.0694 mL	0.3469 mL	0.6937 mL	1.3874 mL	1.7343 mL
100 mM	0.0347 mL	0.1734 mL	0.3469 mL	0.6937 mL	0.8672 mL

CFN95381	New compound 14	N/A	524.5	C₂₄H₂₈O₁₃
CFN99092	Tachioside	109194-60-7	302.3	C₁₃H₁₈O₈
CFN98027	3,4-Dimethoxyphenol	2033-89-8	154.2	C₈H₁₀O₃
CFN97405	3,4-Dimethoxyphenyl beta-D-glucoside	84812-00-0	316.3	C₁₄H₂₀O₈
CFN98343	Phlorin	28217-60-9	288.3	C₁₂H₁₆O₈
CFN99366	2,4,6-Trimethoxyphenol 1-O-beta-D-glucopyranoside	125288-25-7	346.3	C₁₅H₂₂O₉
CFN99329	1,2-Benzenediol	120-80-9	110.1	C₆H₆O₂
CFN90974	Guaifenesin	93-14-1	198.2	C₁₀H₁₄O₄
CFN97778	Pyrocatechol monoglucoside	2400-71-7	272.25	C₁₂H₁₆O₇
CFN99089	Resorcinol	108-46-3	110.1	C₆H₆O₂