3-(hydroxymethyl)cyclopentanone | CAS:113681-11-1

3-(hydroxymethyl)cyclopentanone

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Description:

3-Hydroxymethylcyclopentanone is a precursor to synthesize methyl epijasmonate. 3-Hydroxymethylcyclopentanone compounds, which are useful as intermediates in the preparation of HIV chemokine CCR-5 receptor antagonists.

Targets:

CCR

In vitro:

US6506908[P].2003.

Process for preparing 3-hydroxymethyl-4-(aryl or heterocyclic)-cyclopentanones[Reference: WebLink]

Processes are disclosed for preparing 3-(hydroxymethyl)cyclopentanone compounds, which are useful as intermediates in the preparation of HIV chemokine CCR-5 receptor antagonists.
METHODS AND RESULTS:
A process is described in which the compounds are prepared by opening the cyclopropyl ring of a (1-alkoxycarbonyl-2-oxo)-trans-bicyclo[3.1.0]hexane compound by addition of a nucleophile to the cyclopropyl ring, and then decarboxylating the resulting 2-alkoxycarbonyl-3-(Nu-methyl)-cyclopentanone (Nu=the added nucleophilic group) via base solvolysis. Also described is a process for preparing the bicyclo[3.1.0]hexane precursors by the catalyzed cyclopropanation of a suitable alpha-diazo-beta-ketoester. The preparation of the alpha-diazo-beta-ketoesters and precursors thereto are also disclosed.

3-(hydroxymethyl)cyclopentanone Description

Source:	The herbs of Alangium chinese
Solvent:	Chloroform, Dichloromethane, Ethyl Acetate, DMSO, Acetone, etc.
Storage:	Providing storage is as stated on the product vial and the vial is kept tightly sealed, the product can be stored for up to 24 months(2-8C). Wherever possible, you should prepare and use solutions on the same day. However, if you need to make up stock solutions in advance, we recommend that you store the solution as aliquots in tightly sealed vials at -20C. Generally, these will be useable for up to two weeks. Before use, and prior to opening the vial we recommend that you allow your product to equilibrate to room temperature for at least 1 hour. Need more advice on solubility, usage and handling? Please email to: service@chemfaces.com
After receiving:	The packaging of the product may have turned upside down during transportation, resulting in the natural compounds adhering to the neck or cap of the vial. take the vial out of its packaging and gently shake to let the compounds fall to the bottom of the vial. for liquid products, centrifuge at 200-500 RPM to gather the liquid at the bottom of the vial. try to avoid loss or contamination during handling.

Product Name	3-(hydroxymethyl)cyclopentanone
Price:
CAS No.:	113681-11-1
Catalog No.:	CFN99235
Molecular Formula:	C₆H₁₀O₂
Molecular Weight:	114.1 g/mol
Purity:	>=98%
Type of Compound:	Miscellaneous
Physical Desc.:	Oil
Source:	The herbs of Alangium chinese
Solvent:	Chloroform, Dichloromethane, Ethyl Acetate, DMSO, Acetone, etc.
Download:	COA MSDS SDF Manual
Similar structural:	Comparison (Web) (SDF)
Guestbook:

Size /Price /Stock	10 mM * 100 uL in DMSO / Inquiry / In-stock 10 mM * 1 mL in DMSO / Inquiry / In-stock
Related Libraries	Precursors Compound Library Miscellaneous Compound Library CCR Inhibitor Library

	1 mg	5 mg	10 mg	20 mg	25 mg
1 mM	8.7642 mL	43.8212 mL	87.6424 mL	175.2848 mL	219.106 mL
5 mM	1.7528 mL	8.7642 mL	17.5285 mL	35.057 mL	43.8212 mL
10 mM	0.8764 mL	4.3821 mL	8.7642 mL	17.5285 mL	21.9106 mL
50 mM	0.1753 mL	0.8764 mL	1.7528 mL	3.5057 mL	4.3821 mL
100 mM	0.0876 mL	0.4382 mL	0.8764 mL	1.7528 mL	2.1911 mL

CFN99338	3,4-Dihydro-3,4-dihydroxynaphthalen-1(2H)-one	1220891-22-4	178.2	C₁₀H₁₀O₃
CFN91988	Isoshinanolone	39626-91-0	192.21	C₁₁H₁₂O₃
CFN95404	Tetillapyrone	363136-43-0	242.2	C₁₁H₁₄O₆
CFN90555	Pogostone	23800-56-8	224.26	C₁₂H₁₆O₄
CFN92554	Phellolactone	1190897-23-4	298.3	C₁₃H₁₄O₈
CFN92589	6-Methyl-5,6-dihydropyran-2-one	108-54-3	112.1	C₆H₈O₂
CFN97320	1,6-Dioxaspiro[4.5]decan-2-methanol	83015-88-7	172.2	C₉H₁₆O₃
CFN97768	Buergerinin G	263764-83-6	184.19	C₉H₁₂O₄
CFN97289	4-Hydroxy-4-(methoxycarbonylmethyl)cyclohexanone	81053-14-7	186.2	C₉H₁₄O₄
CFN98829	Rengynic acid	517883-38-4	174.2	C₈H₁₄O₄