Gelsempervine A | CAS:865187-17-3 | Manufacturer ChemFaces

Gelsempervine A

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Gelsempervine A Description

Source:	The herbs of Gelsemium elegans
Solvent:	Chloroform, Dichloromethane, Ethyl Acetate, DMSO, Acetone, etc.
Storage:	Providing storage is as stated on the product vial and the vial is kept tightly sealed, the product can be stored for up to 24 months(2-8C). Wherever possible, you should prepare and use solutions on the same day. However, if you need to make up stock solutions in advance, we recommend that you store the solution as aliquots in tightly sealed vials at -20C. Generally, these will be useable for up to two weeks. Before use, and prior to opening the vial we recommend that you allow your product to equilibrate to room temperature for at least 1 hour. Need more advice on solubility, usage and handling? Please email to: service@chemfaces.com
After receiving:	The packaging of the product may have turned upside down during transportation, resulting in the natural compounds adhering to the neck or cap of the vial. take the vial out of its packaging and gently shake to let the compounds fall to the bottom of the vial. for liquid products, centrifuge at 200-500 RPM to gather the liquid at the bottom of the vial. try to avoid loss or contamination during handling.

Structure Identification:

Symposium on the chemistry of natural products, 2006 (48) :319-324.

New Indole Alkaloids from Gelsemium Plants and their Cytotoxic Activity on Tumor Cells[Reference: WebLink]

Gelseiridone (10) is a new type of alkaloid having a nitrogen-carbon linkage between a gelsenicine-type monoterpenoid indole alkaloid that possesses an α,β-unsaturated ketone residue as well as the N_b-C20 seco-form and a monoterpene unit having an iridoid skeleton.
METHODS AND RESULTS:
Five new sarpagine-type alkaloids, Gelsempervine A (23), gelsempervine B (24), gelsempervine C (25), and gelsempervine D (26), and 19Z-16-epi-voacarpine (27), and one yohimbane-type alkaloid, sempervilam (29) were isolated from G. sempervirens.
CONCLUSIONS:
Spectroscopic data suggest that 23 existed as a C/D ring-opening structure with the keto-amine form (A) in such aprotic solvents as CH3CN, and as a transannular structure with the zwitterionic form (B) in such protic solvents as CH3OH.

Product Name	Gelsempervine A
Price:
CAS No.:	865187-17-3
Catalog No.:	CFN96018
Molecular Formula:	C₂₂H₂₆N₂O₄
Molecular Weight:	382.5 g/mol
Purity:	>=98%
Type of Compound:	Alkaloids
Physical Desc.:	Powder
Source:	The herbs of Gelsemium elegans
Solvent:	Chloroform, Dichloromethane, Ethyl Acetate, DMSO, Acetone, etc.
Download:	COA MSDS SDF
Similar structural:	Comparison (Web) (SDF)
Guestbook:

Size /Price /Stock	10 mM * 100 uL in DMSO / Inquiry / In-stock 10 mM * 1 mL in DMSO / Inquiry / In-stock
Related Libraries	Alkaloids Compound Library

	1 mg	5 mg	10 mg	20 mg	25 mg
1 mM	2.6144 mL	13.0719 mL	26.1438 mL	52.2876 mL	65.3595 mL
5 mM	0.5229 mL	2.6144 mL	5.2288 mL	10.4575 mL	13.0719 mL
10 mM	0.2614 mL	1.3072 mL	2.6144 mL	5.2288 mL	6.5359 mL
50 mM	0.0523 mL	0.2614 mL	0.5229 mL	1.0458 mL	1.3072 mL
100 mM	0.0261 mL	0.1307 mL	0.2614 mL	0.5229 mL	0.6536 mL

CFN97884	Vellosimine	6874-98-2	292.4	C₁₉H₂₀N₂O
CFN92612	(+)-Affinisine	2912-11-0	308.4	C₂₀H₂₄N₂O
CFN96211	Macusine B	6792-07-0	309.4	C₂₀H₂₅N₂O
CFN96170	Spegatrine	47326-53-4	325.4	C₂₀H₂₅N₂O₂
CFN96097	10-Hydroxy-16-epiaffinine	82513-70-0	340.4	C₂₀H₂₄N₂O₃
CFN96181	Pelirine	30435-26-8	354.5	C₂₁H₂₆N₂O₃
CFN96148	Taberpsychine	19452-84-7	308.4	C₂₀H₂₄N₂O
CFN97989	N-Methoxyanhydrovobasinediol	125180-42-9	338.5	C₂₁H₂₆N₂O₂
CFN96030	16-Epivoacarpine	114027-38-2	368.4	C₂₁H₂₄N₂O₄
CFN96018	Gelsempervine A	865187-17-3	382.5	C₂₂H₂₆N₂O₄