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9-Phenylcarbazole
9-Phenylcarbazole
ChemFaces products have been cited in many studies from excellent and top scientific journals
Product Name 9-Phenylcarbazole
Price:
CAS No.: 1150-62-5
Catalog No.: CFN90113
Molecular Formula: C18H13N
Molecular Weight: 243.30 g/mol
Purity: >=98%
Type of Compound: Alkaloids
Physical Desc.: Cryst.
Source:
Solvent: Chloroform, Dichloromethane, Ethyl Acetate, DMSO, Acetone, etc.
Download: COA    MSDS    SDF
Similar structural: Comparison (Web)  (SDF)
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Related Screening Libraries
Size /Price /Stock 10 mM * 100 uL in DMSO / Inquiry / In-stock
10 mM * 1 mL in DMSO / Inquiry / In-stock
Related Libraries
Biological Activity
Description: 9-Phenylcarbazole-based dendrons results in the HOMO energy level of -5.36 eV for the 3rd-generation dendrimer, very close to the work function of the ITO/PEDOT electrode (-5.2 eV), which characteristic is very advantageous for the hole injection and transport materials.
Targets: PGE
9-Phenylcarbazole Description
Source:
Solvent: Chloroform, Dichloromethane, Ethyl Acetate, DMSO, Acetone, etc.
Storage: Providing storage is as stated on the product vial and the vial is kept tightly sealed, the product can be stored for up to 24 months(2-8C).

Wherever possible, you should prepare and use solutions on the same day. However, if you need to make up stock solutions in advance, we recommend that you store the solution as aliquots in tightly sealed vials at -20C. Generally, these will be useable for up to two weeks. Before use, and prior to opening the vial we recommend that you allow your product to equilibrate to room temperature for at least 1 hour.

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After receiving: The packaging of the product may have turned upside down during transportation, resulting in the natural compounds adhering to the neck or cap of the vial. take the vial out of its packaging and gently shake to let the compounds fall to the bottom of the vial. for liquid products, centrifuge at 200-500 RPM to gather the liquid at the bottom of the vial. try to avoid loss or contamination during handling.
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Recently, ChemFaces products have been cited in many studies from excellent and top scientific journals

Cell. 2018 Jan 11;172(1-2):249-261.e12.
doi: 10.1016/j.cell.2017.12.019.
IF=36.216(2019)

PMID: 29328914

Cell Metab. 2020 Mar 3;31(3):534-548.e5.
doi: 10.1016/j.cmet.2020.01.002.
IF=22.415(2019)

PMID: 32004475

Mol Cell. 2017 Nov 16;68(4):673-685.e6.
doi: 10.1016/j.molcel.2017.10.022.
IF=14.548(2019)

PMID: 29149595

ACS Nano. 2018 Apr 24;12(4): 3385-3396.
doi: 10.1021/acsnano.7b08969.
IF=13.903(2019)

PMID: 29553709

Nature Plants. 2016 Dec 22;3: 16206.
doi: 10.1038/nplants.2016.205.
IF=13.297(2019)

PMID: 28005066

Sci Adv. 2018 Oct 24;4(10): eaat6994.
doi: 10.1126/sciadv.aat6994.
IF=12.804(2019)

PMID: 30417089
Calculate Dilution Ratios(Only for Reference)
1 mg 5 mg 10 mg 20 mg 25 mg
1 mM 4.1102 mL 20.5508 mL 41.1015 mL 82.203 mL 102.7538 mL
5 mM 0.822 mL 4.1102 mL 8.2203 mL 16.4406 mL 20.5508 mL
10 mM 0.411 mL 2.0551 mL 4.1102 mL 8.2203 mL 10.2754 mL
50 mM 0.0822 mL 0.411 mL 0.822 mL 1.6441 mL 2.0551 mL
100 mM 0.0411 mL 0.2055 mL 0.411 mL 0.822 mL 1.0275 mL
* Note: If you are in the process of experiment, it's need to make the dilution ratios of the samples. The dilution data of the sheet for your reference. Normally, it's can get a better solubility within lower of Concentrations.
Protocol
Structure Identification:
Org Biomol Chem. 2012 Dec 21;10(47):9481-90.
Starburst dendrimers consisting of triphenylamine core and 9-phenylcarbazole-based dendrons: synthesis and properties.[Pubmed: 23117896 ]
.Novel dendrimers consisting of a triphenylamine core and 1st to 3rd generations of 9-Phenylcarbazole-based dendrons were synthesized by Suzuki coupling reaction through convergent approach.
METHODS AND RESULTS:
Their structures were confirmed by two-dimensional correlated H-H COSY and C-H HSQC NMR spectra, MALDI-TOF MS and elemental analysis. The dendrimers exhibit excellent thermal stability with 5% weight loss temperatures over 540 °C. The computer modeling reveals that the dendrons in dendrimers greatly twisted with the generation, leading to the dendrimers decreased crystalline ability. Of interest is the observation that, for an identical dendrimer, the solid film displays the similar UV absorption and luminescence emission profiles to the solution sample, indicating that, after evaporation of solvent, the rigid dendrimer can well maintain its conformational morphology and the aggregation or stacking of the chromophoric groups is significantly inhibited. All the dendrimers can emit intense fluorescence with narrow full width at half maximum (FWHM) around 46-50 nm. Moreover, with the incremental generation, the quantum efficiencies remarkably increase from 64 to 95%, suggesting that the highly contorted and bulky dendrons effectively decrease energy wastage and non-radiative decay.
CONCLUSIONS:
The synergistic effect of electron-donating triphenylamine core and 9-Phenylcarbazole-based dendrons results in the HOMO energy level of -5.36 eV for the 3rd-generation dendrimer, very close to the work function of the ITO/PEDOT electrode (-5.2 eV), which characteristic is very advantageous for the hole injection and transport materials.
J Org Chem. 2000 Jan 14;65(1):116-23.
Synthesis and characterization of monodendrons based on 9-phenylcarbazole[Pubmed: 10813904]

METHODS AND RESULTS:
A series of 9-Phenylcarbazole ethynylene monodenrons have been prepared by palladium-catalyzed coupling reactions creating well-organized arrays of redox centers. The tert-butyl groups attached to the 3,6-positions of peripheral 9-Phenylcarbazole monomers provide adequate solubility to a limited degree. Trimer and 7-mer monodendrons were prepared using a monomer with 3, 3-diethyltriazene at its focal point. To facilitate purification, the synthesis of 15-mer monodendron, however, required a monomer bearing a 3-hydroxy-3-methyl-but-1-ynyl group at its focal point as a masking group for the terminal acetylene functionality. Although the solubility was limited, high generation monodendrons were found to be readily soluble in carbon disulfide, a solvent of high polarizability.
CONCLUSIONS:
Spectroscopic studies showed that there is limited through-bond conjugation over the monodendrons, but fluorescence studies suggested the presence of long-range through-space interactions in the higher members of the series.
Org Lett. 2007 Oct 25;9(22):4531-4.
Synthesis and properties of dumbbell-shaped dendrimers containing 9-phenylcarbazole dendrons.[Pubmed: 17900196]
We report the synthesis and structural characterization of two dumbbell-shaped dendrimers incorporating 9-Phenylcarbazole units as dendrons, as well as their thermal, morphological, photophysical, and electrochemical properties.
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