Cyclo(D-Phe-L-Pro) | CAS:26488-24-4 | Manufacturer ChemFaces

Cyclo(D-Phe-L-Pro)

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Size /Price /Stock	10 mM * 1 mL in DMSO / $99.2 / In-stock
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Cyclo(D-Phe-L-Pro) Description

Source:	From Phellinus igniarius
Solvent:	Chloroform, Dichloromethane, Ethyl Acetate, DMSO, Acetone, etc.
Storage:	Providing storage is as stated on the product vial and the vial is kept tightly sealed, the product can be stored for up to 24 months(2-8C). Wherever possible, you should prepare and use solutions on the same day. However, if you need to make up stock solutions in advance, we recommend that you store the solution as aliquots in tightly sealed vials at -20C. Generally, these will be useable for up to two weeks. Before use, and prior to opening the vial we recommend that you allow your product to equilibrate to room temperature for at least 1 hour. Need more advice on solubility, usage and handling? Please email to: service@chemfaces.com
After receiving:	The packaging of the product may have turned upside down during transportation, resulting in the natural compounds adhering to the neck or cap of the vial. take the vial out of its packaging and gently shake to let the compounds fall to the bottom of the vial. for liquid products, centrifuge at 200-500 RPM to gather the liquid at the bottom of the vial. try to avoid loss or contamination during handling.

Structure Identification:

Int J Pept Protein Res. 1988 Feb;31(2):157-63.

Potential energy calculations on phenylalanine rotamers in different boat forms of proline-containing cyclic dipeptides.[Pubmed: 3366549]

Previous potential energy calculations have always indicated that the folded conformation is the most stable one for cyclic dipeptides containing benzylic side chains.
METHODS AND RESULTS:
We have carried out intramolecular van der Waals potential energy calculations on Cyclo(D-Phe-L-Pro), N-(N-phenylacetyl-L-alanyl)-cyclo-(L-Phe-D-Pro) and N-(pyruvoyl)-cyclo-(L-Phe-D-Pro) adopting the geometries found in their crystal structures. The calculations made on these compounds, having the peptide skeleton made of the same aminoacid residues but differing in the degree of buckling of the boat, show that there is a dependence between diketopiperazine ring and phenylalanine side-chain conformations. The folded conformer is preferred as long as it is allowed by the degree of buckling of the boat.
CONCLUSIONS:
When the boat becomes highly buckled, as in the case of the pyruvoyl derivative, the folded rotamer is no longer favoured. This is the first energy calculation to demonstrate that the folded rotamer is not always the most stable one.

Product Name	Cyclo(D-Phe-L-Pro)
Price:	$238 / 10mg
CAS No.:	26488-24-4
Catalog No.:	CFN96110
Molecular Formula:	C₁₄H₁₆N₂O₂
Molecular Weight:	244.3 g/mol
Purity:	>=98%
Type of Compound:	Alkaloids
Physical Desc.:	Powder
Source:	From Phellinus igniarius
Solvent:	Chloroform, Dichloromethane, Ethyl Acetate, DMSO, Acetone, etc.
Download:	COA MSDS SDF
Similar structural:	Comparison (Web) (SDF)
Guestbook:

Size /Price /Stock	10 mM * 100 uL in DMSO / Inquiry / In-stock 10 mM * 1 mL in DMSO / Inquiry / In-stock
Related Libraries	Alkaloids Compound Library

	1 mg	5 mg	10 mg	20 mg	25 mg
1 mM	4.0933 mL	20.4666 mL	40.9333 mL	81.8666 mL	102.3332 mL
5 mM	0.8187 mL	4.0933 mL	8.1867 mL	16.3733 mL	20.4666 mL
10 mM	0.4093 mL	2.0467 mL	4.0933 mL	8.1867 mL	10.2333 mL
50 mM	0.0819 mL	0.4093 mL	0.8187 mL	1.6373 mL	2.0467 mL
100 mM	0.0409 mL	0.2047 mL	0.4093 mL	0.8187 mL	1.0233 mL

CFN89034	3,6-Dibenzyl-2-hydroxy-5-methoxypyrazine	132213-65-1	306.36	C₁₉H₁₈N₂O₂
CFN96983	Emeheterone	117333-12-7	322.36	C₁₉H₁₈N₂O₃
CFN90280	Cyclo(Phe-Hpro)	1016899-94-7	260.30	C₁₄H₁₆N₂O₃
CFN90279	Cyclo(Tyr-Hpro)	813461-21-1	276.29	C₁₄H₁₆N₂O₄
CFN90277	Cyclo(Pro-Trp)	67889-75-2	283.33	C₁₆H₁₇N₃O₂
CFN96937	Demethoxyfumitremorgin C	111768-16-2	349.43	C₂₁H₂₃N₃O₂
CFN96930	Fumitremorgin C	118974-02-0	379.46	C₂₂H₂₅N₃O₃
CFN89011	Fumitremorgin B	12626-17-4	479.57	C₂₇H₃₃N₃O₅
CFN90627	Heterophyllin B	145459-19-4	778.95	C₄₀H₅₈N₈O₈
CFN91927	Rubiyunnanin C	1261030-04-9	828.91	C₄₃H₅₂N₆O₁₁